A professional entering into an industrial gas job would want to familiarize themselves with this process as it is the most prominent means of hydrogen production in modern industry. Life cycle assessment of hydrogen production via natural gas. A variety of reforming technologies that might be used in distributed hydrogen production at. Pure hydrogen is also produced by electrolysis of water, an energy demanding process. Steam methane reforming smr is a chemical process used in the gas manufacturing industry to produce hydrogen on a large scale. Thus we concentrated more on design of a complete process plant for hydrogen production from steam reforming of.
Areas where hydrogen is heavily consumed include ammonia production, the cryogenics industry and methanol production table 11. Steam reforming is a hydrogen production process from natural gas. First, steam reforming of natural gas and its implementation as an industrial process is introduced. The combination of steam reforming with carbon capture is briefly discussed in order to make the process carbonneutral. Today, hydrogen is mainly produced by steam reforming fossil fuels such as natural gas. Xiao feng, in computer aided chemical engineering, 2018. Pdf benchscale steam reforming of methane for hydrogen. Natural gas reforming hydrogen can be produced from natural gas using hightemperature steam. Cfd simulation of ethanol steam reforming system for.
The feed materials natural gas, liquid gas or naphtha are endothermically converted with water steam into synthesis gas in catalytic tube reactors. Steam methane reforming smr for hydrogen production. Steam reforming steam reforming is the most widely used technology for. This process is a second generation hydrogen production process but offers a simpler process layout compared to the. Hydrogen production by steam methane reforming the process uses a light hydrocarbon. One of these new methods is chemical looping combustion clc. Pdf production of hydrogen by steam reforming of ethanol. In this work, the required heat for the endothermic steam reforming process is provided by coupling the clc as an unprecedented technique with the.
This model predicts the reforming process for a variety of feed stocks, and reformer configurations. Methanol steam reforming for hydrogen generation via conventional and membrane reactors. The yield of hydrogen as a function of oxygen content is shown in figure 1. From the environmental perspective, because of the increasing level of co2 in the atmosphere, different methods are presented for the separating and capturing of co2 from combustion. Steam methane reforming is the most widely used process for bulk gas production, accounting for 95% of the hydrogen produced in the united states. Review of small stationary reformers for hydrogen production. Steam reforming of coke oven gas for hydrogen production. Pdf production of hydrogen by steam methane reformation. Production of hydrogen platefin reformer catalyst can be a surface coating or a porous insert. Hydrogen your partner for the production and processing. Thus we concentrated more on design of a complete process plant for hydrogen production from steam reforming of natural gas.
Even though hydrogen generated from fossil feedstocks has the advantage of zerotailpipe emissions, the production chain still leaves a carbon footprint. A life cycle assessment lca of hydrogen production via natural gas steam reforming was performed to examine the net emissions of greenhouse gases, as well as other major environmental consequences. Bulk hydrogen production by sorbent enhanced steam. The slna reformer process design is performed with a proprietary incremental kinetic model that was developed inhouse, and refined with data from over sixty years of operating experience. If a biomass such as a switchgrass were used as starting. The hydrogen production by steam reforming of raw biooil obtained by fast pyrolysis of pine sawdust has been studied by valle et al. This process, called steam methane reforming, accounts for about 95% of the hydrogen used today in the u. Click here for full pdf version of this article includes all graphs, charts. Figure 1 combined hydrogen production potential from biomass, wind and solar top and current hydrogen production from natural gas using steammethane reforming smr and potential hydrogen production from coal bottom. The advantages of distributed hydrogen production are the production unit can be located at the consumer refueling site, the unit capacity can be tailored to the sites fueling requirements, and this approach eliminates the need for an extensive hydrogen delivery infrastructure.
The dominate steamreforming processes convert natural gas, lpg or naphtha, with water vapor in the presence of a nickel catalyst, into a hydrogenrich synthesis gas. Steam reforming of natural gas the most economical and highly preferable process with the resources of eritrea is steam reforming of natural gas. Redefining steam methane reformer performance in hydrogen. This article will focus on the shell gasification process sgp and steam reforming for the production of hydrogen, describing the current status of these technologies and presenting an outlook of expected future requirements as well as respective development possibilities. The results obtained in this work indicate that for industrial scale production of hydrogen, only dry reforming dr of natural gas shows any promise for competing with the traditional reforming strategies like steam reforming sr, partial oxidation pox and autothermal reforming atr. Steam reforming is a wellestablished hydrogen production process and has been often used for hydrogen production from a wide variety of hydrocarbons such as natural gas kikuchi et al. In the steam reforming process, a desulfurized hydrocarbon feedstock natural gas, refinery offgas, liquefied petroleum gas or naphtha is preheated, mixed with steam and optionally prereformed before passing a catalyst in a proprietary topfired steam reformer to produce hydrogen, carbon monoxide co and carbon dioxide co 2.
This is largely due to its cost effectivness in obtaining a high level of purity in its produced hydrogen. Due to its maturity, high efficiency, and relatively low cost, steam reforming is considered a viable option for supporting a future hydrogen economy. It was found that the niomgo catalyst possessed good catalytic activity, and the conversions of ch4 and co2 were greatly affected by the reaction temperature and steam carbon sc mole ratio. Hydrogen production by integration of fluidized bed heat. Steam methane reforming simulation hydrogen production hysys tutorial p sims. This paper is focused on the process optimization and decarbonization of h2 production from fossil fuels to promote more efficient approaches. Steam methane reforming simulation hydrogen production. Another method, called partial oxidation, produces hydrogen by burning methane in air. The steam reforming of coke oven gas cog for hydrogen production was investigated over the niomgo solid solution catalysts reduced at high temperatures. Using psa for the purification of steam reformer hydrogen produces the. In its simplest form, the steam methane reforming process for pure hydrogen production consists of four stages as shown in figure 1. Catalytic steam reforming an overview sciencedirect topics. The hydrogen obtained from smr can be used in industrial processes and in fuel cells because of its purity.
Need to match the heat release rate with the steam hydrocarbon reforming rate. May 01, 2010 steam reforming of natural gas at petroleum refining facilities is the predominant means of producing hydrogen in the chemical process industries cpi. Molecular catalysts for hydrogen production from alcohols. Steam reforming of natural gas at petroleum refining facilities is the predominant means of producing hydrogen in the chemical process industries cpi. Methane steam reforming reaction behaviour in a packed. It was found that the niomgo catalyst possessed good catalytic activity, and the conversions of ch4 and co2 were greatly affected by the reaction temperature and steamcarbon sc mole ratio. Usable energy out of a process compared to all energy inputs. Comparison of catalyst geometries for methane steam. Ethanol steam reforming esr proceeds at temperatures in the range of 300600 c, which is signi.
Process intensification of steam reforming for hydrogen production 71 preheating, evaporation and superheating of water, and this also affects the reaction temperature. For this reaction, cobalt 5, 6, nickel 7, or rhodium 8 based catalysts exhibited high activities. Distributed production of hydrogen from natural gas utilizes small scale steam methane reforming technology. Among all these methods, smr steam methane reforming process is considered most feasible for being economically cheap as compared to other methods. The dominant process for industrial hydrogen production today is the steam reforming of natural gas. Additionally, as with all sources of hydrogen, production from biomass will require appropriate hydrogen storage and utilization systems to be developed and deployed. Both steam reforming and partial oxidation produce a. Steam reforming can be performed using fixed or fluidized bed tubular reactor systems. This method is currently the cheapest source of hydrogen. Steam methane reforming smr is a chemical process used in the gas manufacturing industry to.
Hydrogen production via steam reforming of ethyl alcohol. Commercial catalysts used in the steam reforming of biooil or its fractions are designed. Steam reforming or steam methane reforming is a method for producing syngas hydrogen and carbon monoxide by reaction of hydrocarbons with water. This process contains two chemical reactions which ultimately convert water and methane usually in the form of natural gas into pure hydrogen and carbon dioxide. This chapter introduces steam reforming, still the major method of largescale hydrogen gas production. The steam reforming hydrogen plant for many years, steam methane reforming smr has been the leading technology for generation of hydrogen in refining and petrochemical complexes.
Oil and gas refineries1 that specifically relates to hydrogen production, 0nm3h. Steam reforming is the most widespread process for the generation of hydrogenrich synthesis gas from light carbohydrates. Steammethane reforming smr for hydrogen production. The main purpose of this technology is hydrogen production. Bulk hydrogen production by sorbent enhanced steam reforming. Process intensification of steam reforming for hydrogen. The paper will examine the possibilities of co2 capture in a steam reforming based plant, and its impact on the economics of hydrogen production. A typical flowsheet for a linde designed large capacity hydrogen plant is shown in figure 1. Steam methane reforming smr for biogas the process of smr can also be utilized for the production of hydrogen from biogas.
Thermodynamic analysis of hydrogen production via chemical. Methane steam reforming thermally coupled with fuel. Steam methane reforming is the most widely used process for the generation of hydrogen. The hydrogen produced by this process requires purification before it is used in downstream processes. Steam methane reforming hydrogen production air liquide. Steam reforming of coke oven gas for hydrogen production over. Exploring novel hydrogen production processes by integration of steam methane reforming with chemicallooping combustion. Steam reforming is the most widespread process for the generation of hydrogen rich synthesis gas from light carbohydrates. Excess hydrogen is also recovered as a byproduct from various industrial processes. The beneficial effect of hydrogen extraction through a membrane on the yields has been quantified. Pdf basic thermodynamic data on the effect of the conditions of steam reforming of ethanol as a prospective method for the production of hydrogen from.
Life cycle assessment of hydrogen production via natural. The process consists of heating the gas to between 7001100 c in the presence of steam and a nickel catalyst. Lca is a systematic analytical method that helps identify and evaluate the environmental impacts of a specific process or competing processes. Methane steam reforming an overview sciencedirect topics. Figure 1 combined hydrogen production potential from biomass, wind and solar top and current hydrogen production from natural gas using steam methane reforming smr and potential hydrogen production from coal bottom.
Despite the fact that hydrogen can be produced in numerous ways, the most interesting but also promising part is the production of hydrogen through electrolysis of water. Methane steam reforming is a chemical process to produce hydrogen and synthesis gas mixture by combination of steam and methane in a reformer at appropriate temperature and pressure in presence of suitable metalbased catalysts 4. Hydrogen from natural gas via steam methane reforming smr. Methanol steam reforming for hydrogen production chemical. Steam methane reforming is a widelyused process to convert methane into a mixture of hydrogen and carbon monoxide syngas. Design of process plant for producing hydrogen from steam. Nov 09, 2009 the steam reforming of coke oven gas cog for hydrogen production was investigated over the niomgo solid solution catalysts reduced at high temperatures. Cfd simulation of ethanol steam reforming system for hydrogen. The steam methane reforming process can be broken down into five distinct steps. Hydrogen your partner for the production and processing of.